Product ID:861 9090,FLEXICOLOR RA FIXER AND REPLENISHER,CONCENTRATE
MSDS Date:05/01/2000
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CKTJQ

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716 722-5151

Info Phone: 716-722-5151/(800) 242-2424

Preparer: NOT PROVIDED

Cage: 19139

EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS

ROCHESTER, NY 14650-1115 US

Telephone: 716-722-5151/(800) 242-2424

Cage: 19139

WATER

CAS: 7732-18-5

RTECS: ZC0110000

AMMONIUM THIOCYANATE

CAS: 1762-95-4

RTECS: XK7875000

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

AMMONIUM THIOSULFATE

CAS: 7783-18-8

RTECS: XN6465000

SODIUM SULFITE

CAS: 7757-83-7

RTECS: WE2150000

AMMONIUM SULFITE

CAS: 10196-04-0

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXPECTED TO BE A LOW
HAZARD FOR RECOMMENDED HANDLING. IF HYDROGEN CYANIDE GAS IS
LIBERATED, IT MAY CAUSE DIZZINESS, HEADACHE, RAPID RESPIRATION,
RAPID PULSE, UNCONSCIOUSNESS, CONVULSIONS A ND DEATH. SULFITES MAY
LIBERATE SULFUR DIOXIDE GAS WHICH IS IRRITATING TO RESPIRATORY
TRACT. EYES: CAUSES IRRITATION. SKIN: CAUSES IRRITATION. HARMFUL IF
ABSORBED THROUGH SKIN. THIS MATERIAL HAS A LOW POTENTIAL TO CAUSE
ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF HUMAN SKIN
SENSITIZATION HAVE BEEN REPORTED. INGESTION: HARMFUL IF SWALLOWED.
MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NON E - NATIONAL
TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION (OSHA): NONE
Effects of Overexposure:INHALATION: IF HYDROGEN CYANIDE GAS IS
LIBERATED, IT MAY CAUSE DIZZINESS, HEADACHE, RAPID RESPIRATION,
RAPID PULSE, UNCONSCIOUSNESS, CONVULSIONS AND DEATH. SULFITES MAY
LIBERATE SULFUR DIOXIDE GAS WHI CH IS IRRITATING TO RESPIRATORY
TRACT. EYES: CAUSES IRRITATION. SKIN: CAUSES IRRITATION. INGESTION:
MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING,
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.

First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTI ON IF SYMPTOMS OCCUR. SKIN: IMMEDIATELY FLUSH WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. WASH
CONTAMINATED CL OTHING BEFORE REUSE. DESTROY OR THOROUGHLY CLEAN
CONTAMINATED SHOES. INGESTION: INDUCE VOMITING AS DIRECTED BY
MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. CALL A PHYSICIA N OR POISON CONTROL CENTER IMMEDIATELY.

Flash Point:NONE
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE (CO2),
ALCOHOL FOAM
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:SOLUTION CONTAINS A STRONG REDUCING
AGENT. DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT.

Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED TO
PREVENT THE LOSS OF WATER. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES.
KEEP FROM CONTACT WITH OXIDIZING MATERIALS, HIGHLY OXYGENATED OR
HALOGENATED SOLVENTS, ORGANIC COM POUNDS CONTAINING REDUCIBLE
FUNCTIONAL GROUPS, OR AQUEOUS AMMONIA.
Other Precautions:IF ACCIDENTALLY MIXED WITH A STRONG OXIDIZER OR ACID,
DO NOT BREATHE GAS. AVOID BREATHING MIST. AVOID CONTACT WITH EYES,
SKIN, AND CLOTHING. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY
AFTER HANDLI NG.

Respiratory Protection:NONE SHOULD BE NEEDED UNDER NORMAL CONDITIONS OF
USE. HOWEVER IN THE UNLIKELY EVENT THAT HAZARDOUS DECOMPOSITION
PRODUCTS ARE RELEASED, EMERGENCY RESPONSE PERSONNEL MUST WEAR A
FULL-FACE POSITIVE-PRES SURE AIR SUPPLIED RESPIRATOR. IF
RESPIRATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED TO ASSURE
COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING
APPROPRIATE FOR RISK OF EXPOSURE
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:EYE BATH, WASHING FACILITIES.
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
SUPPLEMENTARY LOCAL EXHAUST VENTILATION, CLOSED SYSTEMS, OR RESPIRATORY
PROTECTION MAY BE NEEDED IN SPECIAL CIRCUMSTANCES SUCH AS POORLY
VENTILATED SPACES, EVAPORATION FROM LARGE SURFACES, SPRAYING, H
EATING, ETC.

HCC:N1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:(68?F):24 MBAR (18 MM HG)
Vapor Density:0.6
Spec Gravity:1.168
pH:7.5
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:LIGHT YELLOW LIQUID. ODOR: SLIGHT VINEGAR.
Percent Volatiles by Volume:60-65 WT
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS (E.G. SODIUM HYPOCHLORITE (BLEACH), STRONG
ACIDS (E.G. SULFURIC ACID), BASES, COMBUSTIBLE MATERIAL,
HALOGENATED MATERIALS. CONTACT WITH STRONG OXIDIZING AGENTS OR
ACIDS, LIBERATES POISONOUS GAS AND
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:AMMONIA, CHLORAMINE, CYANIDES,
CARBONYL SULFIDE, SULFUR DIOXIDE. CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF NITROGEN, OXIDES OF SULFUR.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.

Toxicological Information:EFFECTS OF EXPOSURE: GENERAL: CONTAINS:
AMMONIUM THIOCYANATE. OVEREXPOSURE TO THIOCYANATES HAS BEEN
SHOWN TO CAUSE THYROID ENLARGEMENT, DECREASE IN METABOLIC RATE, AND
SYMPTOMS OF HYPOTHYR OIDISM IN HUMANS AND ANIMALS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:POTENTIAL TOXICITY: FISH LC50 MG/L: >100. DAPHNID EC50
MG/L: >100. ALGAL IC50 MG/L: >100. ORGANICS READILY
DEGRADABLE (>70%): YES (14 DAYS). POTENTIAL BIOACCUMULATION: LOG
POW <1. COD (APPROXIMATE G/L): 160. BOD5 (APPROXIMATE G/L):
85. POTENTIAL TOXICITY WASTE TREATMENT MICROORGANISMS EC50
(MG/L): >100

Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD
TIME), MONDAY THROUGH FR IDAY.

SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: AMMONIUM THIOCYANATE, AMMONI UM THIOSULFATE; AS SOURCES
OF AQUEOUS AMMONIA.
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE